What is the effect of increasing concentration on the equilibrium of a chromate/dichromate mixture?

Study for the AS Level Chemistry Exam. Test your knowledge with flashcards and multiple choice questions. Each question comes with hints and explanations. Prepare confidently for your exam!

In a chromate/dichromate equilibrium system, the reaction can be represented as follows:

[ \text{2 CrO}_4^{2-} (aq) \rightleftharpoons \text{Cr}_2\text{O}_7^{2-} (aq) + \text{H}_2\text{O} ]

According to Le Chatelier's Principle, if the concentration of one of the reactants or products in a dynamic equilibrium is changed, the system will adjust itself to counteract that change. In this case, if the concentration of chromate ions (( \text{CrO}_4^{2-} )) is increased, the system responds by shifting the equilibrium to the right, toward the production of dichromate ions (( \text{Cr}_2\text{O}_7^{2-} )). This shift helps to decrease the concentration of chromate ions until a new equilibrium is reached.

Thus, increasing the concentration of chromate ions effectively drives the reaction forward, resulting in the formation of more dichromate ions.

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